The chemical composition of ice and water under ice of Lake Onega (the case of Petrozavodsk Bay)
https://doi.org/10.15356/2076-6734-2018-1-417-428
Abstract
Data on the content of ions, nutrients and organic substance in snow on the ice as well as in the ice and water under ice in the Petrozavodsk Bay and Central part of Onega Lake (March 2017) as well as in the snow cover on the Petrozavodsk Bay shore (2008–2017) are presented. In areas of the Petrozavodsk Bay experiencing anthropogenic and natural impacts, chloride ions prevail among anions in crystallo-hydrates, while sulphate ions are prevalent at the exit from the Bay and in the central part of the lake (clean water). The water under ice has a bicarbonate-calcium composition. Among the inorganic forms of nitrogen compounds (NH4+, NO2, NO3) ammonium ions prevail in the ice(70%), while in snow and the water under ice the prevalent are nitrate ions and organic nitrogen. The content of nitrogen compounds and mineral and total phosphorus is increased in the upper layer of ice. Note, that chemical composition of ice cover is formed by both, a water under the ice and atmospheric precipitation. To determine intensity of involvement of dissolved substances to the ice in combination with ice-forming water, the coefficient of involvement Kv was used. As is shown by our studies, value of the involvement index Kv is individual for each chemical component, however a certain general regularity is observed. Thus, the not proportional relations between contents of ammonium and phosphate ions in ice and water under ice were noticed. The increased involvement indices of NH4+and РО43− into the ice from the water under ice seem to be due to the high rate of migration of these ions together with detachment of them from organic matter molecules.
About the Authors
A. V. SabylinaRussian Federation
Petrozavodsk
T. A. Efremova
Russian Federation
Petrozavodsk
References
1. Prokacheva V.G., Usachev V.F. Severo-Zapadnyi Federal'nyi Okrug Rossii. Zagryaznenie zemli po gorodskim poseleniyam i rayonam, v rechnykh i ozernykh vodosborakh. Northwestern Federal District Contaminated land in urban settlements and areas, in river and lake catchments. Saint Petersburg: Nedra, 2006: 17– 19. [In Russian].
2. Alekseev V.R. Snow cover as an indicator of cumulative land contamination. Led i Sneg. Ice and Snow. 2013, 53 (1): 127–140. doi: 10.15356/2076-6734-2013-1-127-140. [In Russian].
3. Vernadskiy V.I. Izbrannye proizvedeniya. Selected works. Moscow: Publishing House of AN SSSR, 1960: 652 p. [In Russian].
4. Lewis G.J., Thompson T.G. The effect of freezing on the sulfate/chlorinity ratio of sea water. Journ. of Marine Research. 1954, 13 (2): 211–217.
5. Lisitsyn A.P. Unresolved problems in the oceanology of the Arctic. Opyt sistemnykh okeanologicheskikh issledovaniy v Arktike. Experience of systemic oceanological research in the Arctic. Moscow: Nauchnyi mir, 2001: 31–74. [In Russian].
6. Nemirovskaya I.A. Uglevodorody v okeane (sneg – led – voda – donnye osadki). Hydrocarbons in the ocean (snow – ice – water – bottom sediments). PhD Thesis. Moscow: Institute of Oceanology, 2000: 40 p. [In Russian].
7. Nemirovskaya I.A., Chernyavskiy N.G. New data on the distribution of organic compounds in the snow-ice cover of East Antarctica. Led i Sneg. Ice and Snow. 2010, 2 (110): 109–117. [In Russian].
8. Alekin O.A. Tarasov M.N. On the genesis of chemical composition in water of Lake Balkhash. Doklady Akademii Nauk SSSR. Proc. of the USSR Academy of Sciences. 1956, 109 (3): 986–989. [In Russian].
9. Votintsev K.K., Grigorieva E.N. Characteristics of the chemical composition of ice and subglacial water in the lakes of Northern Kazakhstan. Doklady Akademii Nauk SSSR. Proc. of the USSR Academy of Sciences. 1973, 211 (6): 1405–1407. [In Russian].
10. Anisimova N.P., Rogovskaya L.G. The temporal change in the chemical composition of lake ice. Ozera kriolitozony Sibiri. Siberian cryolithozone lakes. Novosibirsk: Nauka. 1974: 128–137. [In Russian].
11. Ivanov A.V. Kriogennaya metamorfizatsiya khimicheskogo sostava prirodnykh l’dov_ zamerzayushchikh i talykh vod. Cryogenic metamorphism of the chemical composition of natural ice, freezing and thawing waters. Khabarovsk: Dalnauka, 1998: 164 p. [In Russian].
12. Osterkamp T.E. Weber A.H. Electrical phenomena accompanying the phase change of dilute KCl solution into single crystals of ice. Journ. of Glaciology. 1970, 9 (56): 269–270.
13. Sabilina A.V. The modern status of hydrochemical regime of Onego Lake. Onezhskoe ozero. Ekologicheskie problemy. Onego Lake. Ecological problems. Petrozavodsk: Karelisn Research Center of RAS, 1999: 58–109. [In Russian].
14. Sabylina A.V., Lozovik P.A., Zobkov M.B. Water chemistry in Onega Lake and in its tributaries. Vodnye Resursy. Water Resources. 2010, 37 (6): 717–729. [In Russian].
15. Boyarinov P.A., Petrov M.I. Processy formirovaniya termicheskogo rezhima glubokikh presnovodnykh vodoemov. Processes of the formation of thermal regime in deep freshwater reservoirs. Leningrad, 1991: 175 p. [In Russian].
16. Balaganskiy A.F., Karpechko V.A., Litvinenko A.V., Salo Yu.A. River flow resources and water balance. Krupneishie ozera-vodokhranilishcha severo-zapada evropeyskoy territorii Rossii: sovremennoe sostoyanie i izmeneniya ekosistem pri klimaticheskikh i antropogennykh vozdeystviyakh. The largest lakes-reservoirs of the North-West European part of Russia: current state and changes of ecosystems under climate variability and antropogenic impact. Petrozavodsk: KarRC RAS, 2015: 31–38. [In Russian].
17. Rukovodstvo po khimicheskomu analizu poverkhnostnykh vod sushi. Ch. 1. Guidelines for the chemical analysis of surface waters. Pt. 1. Rostov-na-Donu: NOK, 2009: 1044 p. [In Russian].
18. Zobkov M.B., Musatova M.V. Ustroystvo dlya opredeleniya organicheskogo ugleroda v vode. Device for determining organic carbon in water. The patent of the Russian Federation. № 148307 29.10.14. [In Russian].
19. Sergeev G.B., Batyuk V.A. Kriokhimiya. Cryochemistry. Moscow: Khimiya, 1978: 296. [In Russian].
20. Vorobieva I.B., Naprasnikova E.V., Vlasova N.V. Ecological and geochemical evaluation of the system: snow on ice – ice – under ice water of Lake Baikal. Trudy Vserossiyskoy konferentsii «Ledovye i termicheskie protcessy na vodnykh ob’ektakh Rossii». All-Russian Conf. «Ice and thermal processes in water bodies of Russia». Moscow, 2007: 87–90. [In Russian].
21. Rozental O.M. Structure and freezing in the ice of hydration complexes of ions. Zhurnal Strukturnoy Khimii. Journ. of Structural Chemistry. 1971, 5: 915–919. [In Russian].
22. Samoylov O.Ya. Struktura vodnykh rastvorov elektrolitov i gidratatsiya ionov. Structure of aqueous solutions of electrolytes and hydration of ions. Moscow: USSR Academy of Sciences, 1957: 182 p. [In Russian].
23. Nechaev E.A., Romanov V.P. Adsorption of anions on ice and freezing potentials. Zhurnal fizicheskoy khimii. Journ. of Physical Chemistry. 1981, 55 (1): 1818–1821. [In Russian].
24. Orlov D.S. Gumusovye kisloty pochv i obshchaya teoriya gumifikatsii. Soil humus acids and general theory of humification. Moscow: MGU, 1999: 328 p. [In Russian].
25. Archegova I.B. The experience of freezing solutions of humic acids. Pochvovedenie. Soil Science. 1967, 6: 57– 63. [In Russian].
26. Komulaynen S., Slastina J., Klochkova M. Winter algae communities in the lakes and rivers ecosystems (Karelia, Russia). Еds. K. Wolowski, I. Kaczmarska, J. Ehrman, A. Wojtal. Current advances in algal taxonomy and its applications: phylogenetic, ecological and applied perspective. Krakow. Poland. W. Szafer Institute of Botany, Polish Academy of Sciences, 2012: 243–251.
27. Melnikov I.A. Winter production of sea ice algae in the western Weddell Sea. Journ. of Marin Systems. 1998, 17: 195–205.
28. Melnikov I.A. Ecosystems of Antarctic sea ice: a comparative analysis. Arktika i Antarktika. Arctic and Antarctic. 2003, 2 (36): 149–164. [In Russian].
29. Pirozhkova G.P. Hydrochemical regime of the lake and its change under the influence of anthropogenic impact. Ekosistema Onezhskogo ozera i tendentsii ee izmeneniya. The ecosystem of Onego Lake and the trends of its change. Leningrad: Nauka, 1990: 95–146. [In Russian].
Supplementary files
For citation: Sabylina A.V., Efremova T.A. The chemical composition of ice and water under ice of Lake Onega (the case of Petrozavodsk Bay). Ice and Snow. 2018;58(3):417-428. https://doi.org/10.15356/2076-6734-2018-1-417-428
Refbacks
- There are currently no refbacks.
ISSN 2076-6734 (Print)
ISSN 2412-3765 (Online)